Primary circuses of experiments
Submitted by sis on 09 December 2007
It’s not some new-age relaxation technique but Bristol ChemLabSw1 – a programme run by the University of Bristol’s chemistry department to take science, chemistry in particular, to the masses. We want to dispel some myths about science being dull, boring, dangerous and/or harmful and also to let the general public see what we really get up to. One of the things we do is visit primary schools.
We start by loading all the equipment, including balloons filled with hydrogen and helium gas, into Tim Harrison’s fortunately large car. On arriving at the school, we unpack and commandeer the school hall for a full demonstration. The children (4-11 years old) file in, staring in wonder and excitement. Once they’ve settled down, with the front rows provided with safety glasses – for effect rather than necessity – Tim gets going. He tests their knowledge by asking the pupils which constituent gases are found in the air. Then he stuns them with liquid nitrogen experiments, dumbfounds them with colourful reactions, makes them giggle with a fountain of bubbles (thank goodness for washing-up liquid) and finishes by exploding the hydrogen balloons with a flame. Of course, we have audience participation for this part. The audience cheer for the fireball, when the hydrogen balloon is set alight, and boo for the boring inert helium balloon which just pops!
For two classes of 9- to 11-year-olds, we have a set of three experiments around which the children rotate, so everybody gets a chance to do all three. I kit the children out in children-sized lab-coats, safety glasses and disposable gloves (they love this!) and get them to team up and dissolve ribbons of magnesium in different concentrations of hydrochloric acid. They measure the time taken for the metal to dissolve, then collect the gas and ignite it so it makes a ‘pop’. The other experiments involve making a colourful polymer – also known as slime - and the iodine clock reaction (see below). The teachers don’t get off lightly either: we put them in lab coats make them join in all the experiments. It surprises me that the children are all so confident and inquisitive: I have to think long and hard when answering some of their questions.
Primary school-university links: a win-win situation?
There are few reasons why chemistry or science workshops cannot be held for primary schools as long as funding and expertise are available. In many countries, primary schools have strong ties with higher educational establishments or their local secondary schools. It should be possible for individual or clusters of schools to seek grants for additional equipment to share or to pay for appropriate groups to come into schoolsw2. The necessary equipment for the most commonly used workshops is listed in the box.
“The pupils spent ages afterwards talking about their favourite demonstration (mainly the washing-up liquid foam one). They were very animated and clearly in awe of what they had seen. Even those younger children who cried [due to a minor – intended – explosion] thought it had been great.”
“[Tim] did some experiments with carbon dioxide and liquid nitrogen, eggs, flowers, gloves, rubber tubing, etc., which have converted … 240 children in half an hour - including all of the ‘uncool to learn’ crew! We are now changing our curriculum to include more of such activities. Schools need lots more of the same. It was wonderful to see the children so motivated.”
“I did not know that gases could freeze.”
“I had expected them to gasp in amazement at the pretty colours, steaming vacuum flasks and loud explosions that Tim created in the school hall but it was their reaction to the classroom experiments that impressed me most. Despite their obvious excitement, their behaviour was exemplary and they were a real credit to the school. Plus, by the end of the final 30-minute session, every pair in my group was able to predict to the nearest second a fairly complicated clock reaction! From the kids’ point of view, we definitely succeeded in making science ‘cool’!”
Bristol ChemLabS’s equipment for primary-school workshops includes:
The apparatus, storage boxes, chemicals, and other consumables for the day’s visit cost about UK£4000, including the equipment for the morning presentation to the whole school.
Practical details for the chemistry workshops
A classroom (with a sink) is easily converted into a temporary laboratory. Although we offer several experiments, the most popular ones are those designed to increase measurement, investigatory and cooperation skills and an increased awareness of chemical safety. These are described below.
Many secondary-school teachers may recognise the experiments, but the purpose of running them in primary schools is not to get the pupils to produce written records. They may do this later with their teachers, but the main point is to show the children how exciting and how much fun science can be.
Note: All chemical use should have a risk assessment made by the people conducting the experiment and must take into account local conditions. Primary teachers who do not have a background in chemistry may feel more comfortable obtaining the following solutions from colleagues in their local secondary school.
Investigating the properties of slime and polymorph
Slime is made by mixing borax and poly(vinyl alcohol) (PVA) solutions, then adding a few drops of food colouring. Changing the proportion of borax changes the physical properties of the slime. This (rather yucky) experiment is very popular with children.
Polymorph is a thermoplastic that can be moulded at the comparatively low temperature of 62°C.
For two classes of 35 pupils working in pairs, you will need 3 l of PVA solution and 2 l of borax solution.
To make 1 l of PVA solution:
To make 1 l of 4% borax solution:
Note: Borax is also called sodium borate or sodium tetraborate, and is widely used in detergents, water softeners, soaps and disinfectants.
Polymorph can be bought from Middlesex University Teaching Resources, UKw3 for about €30/kg. Allow 4-5 g per pupil (in individual tubes).
Introduce the pupils to the thermoplastic polymorph. This comes as colourless granules which, when put into hot water (over 62°C), can be moulded into interesting shapes such as fish, birds or – for the less imaginative – balls. The balls made from this material bounce differently depending on whether the polymer is still warm or has reformed its bonds in the coloured form.
The iodine clock experiment
With this experiment, the children investigate dilution and learn how to measure volume accurately to make the chemical reaction change colour after exactly 30 seconds. We run this activity as a competition, which adds to the fun.
The experiment uses two solutions referred to simply as solution A and solution B (see below). We do not confuse the issue with the names of the chemicals used. Students have three small beakers half-filled with solution A, solution B and water (W) and appropriately marked measuring cylinders to avoid contamination.
For two classes of 35 pupils, you will need 4 l of each solution.
To make 4 l of solution A, mix the following chemicals and add water until the total volume is 4 l:
To make 4 l of solution B, take 200 ml (30%, also described as 100 Vol) hydrogen peroxide and add water until the total volume is 4 l.
Make sure that each pair of students has the correct equipment and can operate a stopwatch, then demonstrate the reaction without dilution. Mix 15 ml of solution A and solution B together. The mixture will turn black after several seconds.
Discuss the effect of adding water to the mixture. Use terms such as ‘less concentrated’ and ‘more dilute’ in the explanation, to give the pupils a mental model of what is happening. Give all instructions verbally to maximise the time spent doing the practical.
Set the children the challenge of making the mixture turn black at a set time – set a target that is between 30 and 60 seconds. Give each pair of children a different time to achieve.
Although the experiment is not strictly a fair test, as both the volume and concentration of the mixture changes, it does excite the pupils as well as giving them practice in measuring, investigating and how to work in a team. If necessary, you could offer a reward to the best pair.
It can be made more complex for secondary-school students, for example by insisting that solution B is diluted such that the same volume of solution B is used each time – which is of course more scientifically appropriate.
After the experiment, carefully pour the iodine solution that has been produced into a sink and wash it away. Wipe and reuse the beakers. If you do not have a sink, use a waste bucket (containing sodium thiosulphate crystals to react with the iodine) and dispose of the solution in a toilet at intervals.
The pupils enjoy investigating the effect of diluting an acid on its reaction with magnesium, especially because they get to collect the hydrogen and set it alight (with a loud pop) at the end.
When we do the experiment, the postgraduate scientist shows the pupils how to ignite the gas and supervises them carefully while they do it themselves.
w1 – For more information about Bristol ChemLabS, see: www.chemlabs.bristol.ac.uk
w2 – A list of sources of potential funding for schools activities in the UK can be downloaded from the Bristol ChemLabS website: www.chemlabs.bristol.ac.uk/outreach/resources/
Editor’s note: If you know of a similar list of funding sources that apply to other European countries, email the web link to firstname.lastname@example.org and we can include it on the Science in School website.
w3 - Middlesex University Teaching Resources website: www.mutr.co.uk
Details of some of Bristol ChemLabS’s activities for secondary schools are described in:
Harrison T, Shallcross D (2006) Perfume chemistry, sexual attraction and exploding balloons: university activities for school. Science in School 3: 48-51. www.scienceinschool.org/2006/issue3/perfume
This article describes visits by university students to primary schools to do chemical experiments, motivating the pupils, inspiring interest in chemistry, and provoking astonishment and joy.
There are detailed descriptions of the experiments, which could be used even by teachers without extensive experience in chemistry or access to a laboratory. I will definitely do the iodine clock experiment with my chemistry students.
Alex Griffen is now a postdoctoral research associate at the Synchrotron Radiation Source, UK.
Tim Harrison is the Bristol ChemLabS School Teacher Fellow.
Dudley Shallcross is a professor of atmospheric chemistry at the University of Bristol and the Bristol ChemLabS outreach director.